Origin of K-rich diamond-forming immiscible melts and CO2 fluid via partial melting of carbonated pelites at a depth of 180–200 km     

《Gondwana Research》2019

Melt inclusions in kimberlitic and metamorphic diamonds worldwide range in composition from potassic aluminosilicate to alkali-rich carbonatitic and their low-temperature derivative, a saline high-density fluid (HDF). The discovery of CO₂ inclusions in diamonds containing eclogitic minerals are also essential. These melts and HDFs may be responsible for diamond formation and metasomatic alteration of mantle rocks since the late Archean to Phanerozoic. Although a genetic link between these melts and fluids was suggested, their origin is still highly uncertain. Here we present experimental results on melting phase relations in a carbonated pelite at 6 GPa and 900–1500 °C. We found that just below solidus K₂O enters potassium feldspar or K₂TiSi₃O₉ wadeite coexisting with clinopyroxene, garnet, kyanite, coesite, and dolomite. The potassium phases react with dolomite to produce garnet, kyanite, coesite, and potassic dolomitic melt, 40(K_0.90Na_0.10)₂CO₃·60Ca_0.55Mg_0.24Fe_0.21CO₃ + 1.9 mol% SiO₂ + 0.7 mol% TiO₂ + 1.4 mol% Al₂O₃ at the solidus established near 1000 °C. Molecular CO₂ liberates at 1100 °C. Potassic aluminosilicate melt appears in addition to carbonatite melt at 1200 °C. This melt contains (mol/wt%): SiO₂ = 57.0/52.4, TiO₂ = 1.8/2.3, Al₂O₃ = 8.5/13.0, FeO = 1.4/1.6, MgO = 1.9/1.2, CaO = 3.8/3.2, Na₂O = 3.2/3.0, K₂O = 10.5/15.2, CO₂ = 12.0/8.0, while carbonatite melt can be approximated as 24(K_0.81Na_0.19)₂CO₃·76Ca_0.59Mg_0.21Fe_0.20CO₃ + 3.0 mol% SiO₂ + 1.6 mol% TiO₂ + 1.4 mol% Al₂O₃. Both melts remain stable to at least 1500 °C coexisting with CO₂ fluid and residual eclogite assemblage consisting of K-rich omphacite (0.4–1.5 wt% K₂O), almandine-pyrope-grossular garnet, kyanite, and coesite. The obtained immiscible alkali‑carbonatitic and potassic aluminosilicate melts resemble compositions of melt inclusions in diamonds worldwide. Thus, these melts entrapped by diamonds could be derived by partial melting of the carbonated material of the continental crust subducted down to 180–200 km depths. Given the high solubility of chlorides and water in both carbonate and aluminosilicate melts inferred in previous experiments, the saline end-member, brine, could evolve from potassic carbonatitic and/or silicic melts by fractionation of Ca-Mg carbonates/eclogitic minerals and accumulation of alkalis, chlorine and water in the residual low-temperature supercritical fluid. Direct extraction from the hydrated marine sediments under conditions of cold subduction would be another possibility for the brine formation.  相似文献   

The effects of simulated inundation duration and frequency on litter decomposition: A one-year experiment     

《Limnologica》2019

There is major uncertainty in the responses of litter decomposition to the inundation regimes in field studies, mainly because of the difficulties in identification of the individual effect of duration and frequency using field studies alone. The interactive role of inundation regime and litter quality also remains unclear. The responses of mass loss to simulated inundation regime (duration and frequency) and litter quality were investigated in leaves of Carex brevicuspis and leaves and stems of Miscanthus sacchariflorus from Dongting Lake, China. Three litter types differing in litter quality were incubated under seven different inundations over 360 days (three single inundations of 90, 180, and 360 days; three repeated 180-day inundations of 2, 3, and 6 times; and no inundations) in a pond near Dongting Lake. Initial N and P contents were highest in C. brevicuspis leaves, intermediate in M. sacchariflorus leaves, and lowest in M. sacchariflorus stems, whereas the organic C, cellulose, and lignin contents were ranked in the opposite order among the three litter types. Decomposition rate was highest in M. sacchariflorus leaves (0.00222–0.00900 day⁻¹), intermediate in C. brevicuspis leaves (0.00135–0.00500 day⁻¹), and lowest in M. sacchariflorus stems (0.00080–0.00100 day⁻¹). The decomposition rate of both C. brevicuspis and M. sacchariflorus leaves increased with increasing inundation duration or decreasing frequency. However, both duration and frequency of inundation had no effect on decomposition of M. sacchariflorus stems. At the end of the incubation, N mineralization was complete in leaf litters with increasing rates with increasing inundation duration or decreasing inundation frequency, but accumulation was found in M. sacchariflorus stems. Organic C decayed quickly in both leaf litters compared with the stem litter. These data indicate that inundation regime has no effect on the decomposition of refractory stem litter while prolonged and stable inundation stimulates the degradation of labile leaf litter.  相似文献   

Geological and tectonic evolution of the Transantarctic Mountains,from ancient craton to recent enigma     

《Gondwana Research》2020

The Transantarctic Mountains (TAM) are one of Earth's great mountain belts and are a fundamental physiographic feature of Antarctica. They are continental-scale, traverse a wide range of latitudes, have high relief, contain a significant proportion of exposed rock on the continent, and represent a major arc of environmental and geological transition. Although the modern physiography is largely of Cenozoic origin, this major feature has persisted for hundreds of millions of years since the Neoproterozoic to the modern. Its mere existence as the planet's longest intraplate mountain belt at the transition between a thick stable craton in East Antarctica and a large extensional province in West Antarctica is a continuing enigma. The early and more cryptic tectonic evolution of the TAM includes Mesoarchean and Paleoproterozoic crust formation as part of the Columbia supercontinent, followed by Neoproterozoic rift separation from Laurentia during breakup of Rodinia. Development of an Andean-style Gondwana convergent margin resulted in a long-lived Ross orogenic cycle from the late Neoproterozoic to the early Paleozoic, succeeded by crustal stabilization and widespread denudation during early Gondwana time, and intra-cratonic and foreland-basin sedimentation during late Paleozoic and early Mesozoic development of Pangea. Voluminous mafic volcanism, sill emplacement, and layered igneous intrusion are a primary signature of hotspot-influenced Jurassic extension during Gondwana breakup. The most recent phase of TAM evolution involved tectonic uplift and exhumation related to Cenozoic extension at the inboard edge of the West Antarctic Rift System, accompanied by Neogene to modern glaciation and volcanism related to the McMurdo alkaline volcanic province. Despite the remote location and relative inaccessibility of the TAM, its underlying varied and diachronous geology provides important clues for reconstructing past supercontinents and influences the modern flow patterns of both ice and atmospheric circulation, signifying that the TAM have both continental and global importance through time.  相似文献   

Volatile element chemistry during accretion of the earth     

《Chemie der Erde / Geochemistry》2020,80(1):125594

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献   

Geochemical characteristics of a pre-Middle Jurassic oceanic crust fragment from the Central Pontides in northern Turkey: Geodynamic implications on intra-oceanic subduction initiation     

《Chemie der Erde / Geochemistry》2020,80(1):125535

The Central Pontides (northern Turkey) is one of the key localities to understand the geodynamic evolution of the Palaeo- and Neotethyan oceans. It consists of the pre-Jurassic basement units, the Early Jurassic and the Early Cretaceous accretionary complexes, the widespread Middle Jurassic continental arc magmatics and the Late Jurassic to Tertiary cover units. The Early Cretaceous accretionary complex is represented by the Central Pontide Structural Complex and includes the Middle Jurassic oceanic units, which were metamorphosed during the Early Cretaceous. Apart from these oceanic units, a few metaophiolite and serpentinite fragments have been recognized within the basement units, which may represent the remnants of an older ocean. The pre-Middle Jurassic Devrekani Metaophiolite is the largest oceanic fragment and tectonically intercalated within/between the Devrekani Metamorphics and the Çangaldağ Metamorphic Complex. It is mainly composed of harzburgites, dunites with chromite veins and metagabbros, and cut by metabasaltic andesites and metadacites. Petrographically, the gabbro consists mainly of plagioclase and clinopyroxene, and displays phaneritic/porphyritic texture. In contrast, the metabasaltic andesite includes plagioclase and mica phenocrysts within a fine-grained groundmass. Also, the metadacite is composed predominantly of quartz, plagioclase, and mica minerals. Two different magmatic groups belonging to completely different tectono-magmatic settings have been geochemically determined based on the immobile trace element systematics. The metadacites and metabasaltic andesites are akin to continental arc magmatics and characterized by negative Nb and Ta anomalies and depleted HFSE relative to Th and La contents. However, the metagabbro samples display the geochemical signatures of boninitic rocks and characterized by highly depletion in HFSEs and REEs relative to N-MORB. The Devrekani Metaophiolite in the Central Pontides may represent another remnant of pre-Middle Jurassic oceanic crust generation and can be north-eastward continuation of the Permian-aged Almacık complex and the Boğazköy Metaophiolite fragment in the western Sakarya Composite Terrane. It may have been cut by intrusions of the extensive Middle Jurassic continental arc magmatism after its imbrication within the basement unit. The presence of pre-Middle Jurassic oceanic units may indicate that the Paleozoic ocean may have survived as the Jurassic Intra-Pontide Ocean between the Scythian Platform and Sakarya Composite Terrane during the Mesozoic time. Thus, the Intra-Pontide Suture may normally include the Palaeozoic and Mesozoic remnants of the long-lived northward subducting Tethyan ocean.  相似文献   

Regeneration and utilization of nutrients during collapse of a <Emphasis Type="Italic">Mesodinium rubrum</Emphasis> red tide and its influence on phytoplankton species composition     

Yafeng Zhang  Xiuxian Song  Paul J. Harrison  Sheng Liu  Zhiming Yu  Jinjun Kan  Peiyuan Qian  Hao Liu  Kedong Yin 《中国科学:地球科学(英文版)》2018,61(10):1384-1396

High-biomass red tides occur frequently in some semi-enclosed bays of Hong Kong where ambient nutrients are not high enough to support such a high phytoplankton biomass. These high-biomass red tides release massive inorganic nutrients into local waters during their collapse. We hypothesized that the massive inorganic nutrients released from the collapse of red tides would fuel growth of other phytoplankton species. This could influence phytoplankton species composition. We tested the hypothesis using a red tide event caused by Mesodinium rubrum (M. rubrum) in a semi-enclosed bay, Port Shelter. The red tide patch had a cell density as high as 5.0×10⁵ cells L^?1, and high chlorophyll a (63.71 μg L^?1). Ambient inorganic nutrients (nitrate: \(\rm{NO}_3^-\), ammonium: \(\rm{NH}_4^+\), phosphate: \(\rm{PO}_4^{3-}\), silicate: \(\rm{SiO}_4^{3-}\)) were low both in the red tide patch and the non-red-tide patch (clear waters outside the red tide patch). Nutrient addition experiments were conducted by adding all the inorganic nutrients to water samples from the two patches followed by incubation for 9 days. The results showed that the addition of inorganic nutrients did not sustain high M. rubrum cell density, which collapsed after day 1, and did not drive M. rubrum in the non-red-tide patch sample to the same high-cell density in the red tide patch sample. This confirmed that nutrients were not the driving factor for the formation of this red tide event, or for its collapse. The death of M. rubrum after day 1 released high concentrations of \(\rm{NO}_3^-\), \(\rm{PO}_4^{3-}\), \(\rm{SiO}_4^{3-}\), \(\rm{NH}_4^+\), and urea. Bacterial abundance and heterotrophic activity increased, reaching the highest on day 3 or 4, and decreased as cell density of M. rubrum declined. The released nutrients stimulated growth of diatoms, such as Chaetoceros affinis var. circinalis, Thalassiothrix frauenfeldii, and Nitzschia sp., particularly with additions of \(\rm{SiO}_4^{3-}\) treatments, and other species. These results demonstrated that initiation of M. rubrum red tides in the bay was not directly driven by nutrients. However, the massive inorganic nutrients released from the collapse of the red tide could induce a second bloom in low-ambient nutrient water, influencing phytoplankton species composition.  相似文献   

Hydrologic implications of the isotopic kinetic fractionation of open-water evaporation     

Wei Xiao  Yufei Qian  Xuhui Lee  Wei Wang  Mi Zhang  Xuefa Wen  Shoudong Liu  Yongbo Hu  Chengyu Xie  Zhen Zhang  Xuesong Zhang  Xiaoyan Zhao  Fucun Zhang 《中国科学:地球科学(英文版)》2018,61(10):1523-1532

The kinetic fractionation of open-water evaporation against the stable water isotope H_2 ~(18)O is an important mechanism underlying many hydrologic studies that use ~(18)O as an isotopic tracer. A recent in-situ measurement of the isotopic water vapor flux over a lake indicates that the kinetic effect is much weaker(kinetic factor 6.2‰) than assumed previously(kinetic factor14.2‰) by lake isotopic budget studies. This study investigates the implications of the weak kinetic effect for studies of deuterium excess-humidity relationships, regional moisture recycling, and global evapotranspiration partitioning. The results indicate that the low kinetic factor is consistent with the deuterium excess-humidity relationships observed over open oceans.The moisture recycling rate in the Great Lakes region derived from the isotopic tracer method with the low kinetic factor is a much better agreement with those from atmospheric modeling studies than if the default kinetic factor of 14.2‰ is used. The ratio of transpiration to evapotranspiration at global scale decreases from 84±9%(with the default kinetic factor) to 76±19%(with the low kinetic factor), the latter of which is in slightly better agreement with other non-isotopic partitioning results.  相似文献   

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

地面稠密观测资料在强对流天气监测预警中的研究进展     

李佩芝  周长春  华维 《云南地理环境研究》2020,(1):53-58

综述国内外数篇论文,从强对流天气监测、预报预警、模式同化3个方面总结分析了近年来地面稠密观测资料的应用与优劣之处。综述表明:地面加密自动站、风廓线雷达、地基GPS、雨滴谱仪等多种观测仪器组成的地面稠密观测网具有时间尺度密集、覆盖面积广泛、能捕捉较多细微变化的优势,通过该观测网所得数据总结出的一系列指示性指标在强对流监测预警中具有重要的指示意义。但因中国地形天气情况复杂多变、数据缺失、仪器造价昂贵等问题,导致该观测网所得指示性指标不能适用于中国全境,应根据该观测网数据分析总结适应本地的预报指标。  相似文献   

Rising grain prices in response to phased climatic change during 1736–1850 in the North China Plain     

Wen  Yanjun  Fang  Xiuqi  Liu  Yang  Li  Yikai 《中国科学:地球科学(英文版)》2019,62(11):1832-1844

Grain price volatility during historical periods is regarded as an important indicator of the impact of climate change on economic system, as well as a key link to adjust food security and social stability. The present study used the wheat prices in Baoding Prefecture, China, during 1736–1850 to explore connections between climatic transition and grain price anomalies in the North China Plain. The main findings were as follows:(1) The grain price change showed an apparent correspondence with climatic transition. The period 1781–1820 was a transition phase, with more extremes and decreased precipitations when the climate shifted from a warm phase to a cold one. Corresponding with the climatic transition, the grain price during 1781–1820 was characterized by that the mean of the original grain price series was significantly higher(lower) than the previous(later)phase, and the variance and anomaly amplitude of the detrended grain price series was the highest during 1736–1850.(2) The correspondence between grain price extremes and drought events occurred in phases. Five grain price extremes occurred following drought events during 1781–1810, while extreme droughts were the direct cause of the grain price spike during 1811–1820.(3) Social stability affected by climate change also played an important role in the grain price spike between 1811 and 1820. Paralleling the pathway of "precipitation-grain production-grain price", climate change could have an impact on grain price via the pathway of "precipitation-grain production-grain price-famine-uprising-grain price", as shown during the Tianli Uprising in 1813. These findings could contribute to an improved understanding of the interaction between climate change and human society during the historical period.  相似文献